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1254 If pure liquid H2SO4 at 30015 K (27 C) is added adiabatically to pure liquid water at 30015 K (27 C) to form a 40 mass-% solution, what is the final temperature of the solution 1255 A liquid solution containing 09 kmol H2S04 and 68 kmol H 2 0 at 31115 K (38 C) absorbs 045 kmol of S03(g), also at 31115 K (3S C), forming a more concentrated sulfuric acid solution If the process occurs isothermally, determine the heat transferred 1256 Determine the heat of mixing A H of sulfuric acid in water and the partial specific enthalpies of H2S04and H 2 0 for a solution containing 65 mass-% H2SO4at 29815 K (25 C) 1257 It is proposed to cool a stream of 75 mass-% sulfuric acid solution at 33315 K (60 C) by diluting it with chilled water at 27715 K (4 C) Determine the amount of water that must be added to 045 kg of 7 5 % acid before cooling below 33315 (60 C) actually occurs 1258 The following liquids, all at atmospheric pressure and 32215 K (49"C), are mixed: 113 kg of pure water, 40 kg of pure sulfuric acid, and 34 kg of 25 mass-% sulfuric acid (a) How much heat is liberated if mixing is isothermal at 32215 K (49"C) (b) The mixing process is carried out in two steps: First, the pure sulfuric acid and the 25 mass-% solution are mixed, and the total heat of part (a) is extracted; second, the pure water is added adiabatically What is the temperature of the intermediate solution formed in the first step 1259 A large quantity of very dilute aqueous NaOH solution is neutralized by addition of the stoichiometric amount of a 10-mol-% aqueous HC1 solution Estimate the heat effect per mole of NaOH neutralized if the tank is maintained at 29815 K (25 C) and 1 atm and the neutralization reaction goes to completion Data:.

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] As you can see, by calling sleep( ), the call( ) method allows execution to switch to another thread This results in the mixed-up output of the three message strings In this program, nothing exists to stop all three threads from calling the same method, on the same object, at the same time This is known as a race condition, because the three threads are racing each other to complete the method This example used sleep( ) to make the effects repeatable and obvious In most situations, a race condition is more subtle and less predictable, because you can't be sure when the context switch will occur This can cause a program to run right one time and wrong the next To fix the preceding program, you must serialize access to call( ) That is, you must restrict its access to only one thread at a time To do this, you simply need to precede call( )'s definition with the keyword synchronized, as shown here: class Callme { synchronized void call(String msg) { This prevents other threads from entering call( ) while another thread is using it After synchronized has been added to call( ), the output of the program is as follows: [Hello] [Synchronized] [World] Any time that you have a method, or group of methods, that manipulates the internal state of an object in a multithreaded situation, you should use the synchronized keyword to guard the state from race conditions Remember, once a thread enters any synchronized method on an instance, no other thread can enter any other synchronized method on the same instance However, nonsynchronized methods on that instance will continue to be callable

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For NaC1, lim A = 388 kJ mol-' %

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While creating synchronized methods within classes that you create is an easy and effective means of achieving synchronization, it will not work in all cases To understand why, consider the following Imagine that you want to synchronize access to objects of a class that was not designed for multithreaded access That is, the class does not use synchronized methods Further, this class was not created by you, but by a third party, and you do not have access to the source code Thus, you can't add synchronized to the appropriate methods within the class How can access to an object of this class be synchronized Fortunately, the solution to this problem is quite easy: You simply put calls to the methods defined by this class inside a synchronized block This is the general form of the synchronized statement: synchronized(object) { // statements to be synchronized } Here, object is a reference to the object being synchronized If you want to synchronize only a single statement, then the curly braces are not needed A synchronized block ensures that a call to a method that is a member of object occurs only after the current thread has successfully entered object's monitor Here is an alternative version of the preceding example, using a synchronized block within the run( ) method: // This program uses a synchronized block

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