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for pure liquid H2S04 at 29815 K (25 C) In this case the 27315 K ( P C ) isotherm terminates at H = 0 at the end of the diagram representing pure liquid H20, and the 29815 K (25 C) isotherm terminates at H = 0 at the other end of the diagram representing pure liquid H2S04 The advantage of taking H = 0 for pure liquid water at its triple point is that this is the base of the steam tables Enthalpy values from the steam tables can then be used in conjunction with values taken from fhe enthalpylconcentration diagram Were some other base used for the diagram, one would have to apply a correction to the steam-table values to put them on the same basis as the diagram For an ideal solution, isotherms on an enthalpylconcentration diagram are straight lines connecting the enthalpy of pure species 2 at xl = 0 with the enthalpy of pure species 1 at = 1, as illustrated for a single isotherm in Fig 1218 by the dashed line The solid curve represents an isotherm for a real solution Also shown is a tangent line from which partial enthalpies may be determined in accord with Eqs (1115) and (1116) Equations (1179) and (1240) combine to give A H = H - H"; A H is therefore the vertical distance between the curve and the dashed line of Fig 1218 Here, the actual isotherm lies below the ideal-solution isotherm, and AH is everywhere negative This means that heat is evolved whenever the pure species at the given temperature are mixed to form a solution at the same temperature Such a system is exothermic The H2S04/H20system is an example An endothermic system is one for which the heats of solution are positive; in this case heat is absorbed to keep the temperature constant An example is the methanolhenzene system One feature of an enthalpylconcentration diagram which makes it particularly useful is the ease with which problems involving adiabatic mixing may be solved The reason is that all solutions formed by adiabatic mixing of two solutions are represented by points lying on a straight line connecting the points that represent the initial solutions This is shown as follows.
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VaporAiquid equilibrium (VLE) is the state of coexistence of liquid and vapor phases In this qualitative discussion, we limit consideration to systems comprised of two chemical species, because systems of greater complexity cannot be adequately represented graphically When N = 2, the phase rule becomes F = 4 - nSince there must be at least one phase(n = I), the maximum number of phase-rule variables which must be specified to fix the intensive state of the system is three: namely, P, T, and one mole (or mass) fraction All equilibrium states of the system can therefore be represented in three-dimensional P-Tcomposition space Within this space, the states of pairs of phases coexisting at equilibrium (F = 4 - 2 = 2) define surfaces A schematic three-dimensional diagram illustrating these surfaces for VLE is shown in Fig 101 This figure shows schematically the P-T-composition surfaces which contain the equilibrium states of saturated vapor and saturated liquid for a binary system The under surface contains the saturated-vapor states; it is the P-T-yl surface The upper surface contains the saturated-liquid states; it is the P-T-xl surface These surfaces intersect along the lines U B H C ,
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